Use the results of Problem 16 to calculate the vibrational frequency of the LiCl molecule. To do
Question:
Use the results of Problem 16 to calculate the vibrational frequency of the LiCl molecule. To do this, expand the potential about r = r0 where r0 is the equilibrium separation, in a Taylor series. Retain only the term proportional to (r- r0)2. Recall that the potential energy of a simple harmonic oscillator is given by V = ½mω2x2. What is the wavelength resulting from transitions between adjacent harmonic oscillator levels of this molecule?
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We have Ur ke 2 r Cr n neglecting the constant term E Also nU rep r 0 ke 2 r 0 nCr ...View the full answer
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1st Edition
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