Consider the PtS net listed in Table 1.6. The dehydrated form of MOF-11 has composition Cu 2

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Consider the PtS net listed in Table 1.6. The dehydrated form of MOF-11 has composition Cu2(ATC) where ATC is 1,3,5,7-adamantane tetracarboxylate and contains a Cu paddle-wheel unit analogous to the Zn dimer shown in Figure 14.13. Describe the structure of PtS. Based on the information given and your chemical knowledge, suggest possible structures for MOF-11 and ZnPt(CN)4.

Table 1.6

N.M 4,2 4,3 4,3 4,4 4.4 4,4 6,2 6,3 6,4 6,6 6,6 8,4 8,8 Cation coordination Tetrahedron Tetrahedron Square

Figure 14.13

COH COH COH COH COH square Zn dimer COH HOC bdc bpdc tpdc COH btc trigonal prism FeO bipy octahedron Zn0 NC-

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Solid State Materials Chemistry

ISBN: 9780521873253

1st Edition

Authors: Patrick M. Woodward, Pavel Karen, John S. O. Evans, Thomas Vogt

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