Question: A 1.509-g sample of a Pb/Cd alloy was dissolved in acid and diluted to exactly 250.0 mL in a volumetric flask. A 50.00-mL aliquot of
A 1.509-g sample of a Pb/Cd alloy was dissolved in acid and diluted to exactly 250.0 mL in a volumetric flask. A 50.00-mL aliquot of the diluted solution was brought to a pH of 10.0 with a NH4+/NH3 buffer; the subsequent titration involved both cations and required 28.89 mL of 0.06950 M EDTA. A second 50.00-mL aliquot was brought to a pH of 10.0 with an HCN/NaCN buffer, which also served to mask the Cd2+; 11.56 mL of the EDTA solution were needed to titrate the Pb2+. Calculate the percent Pb and Cd in the sample.
Step by Step Solution
3.34 Rating (166 Votes )
There are 3 Steps involved in it
Amount Cd Pb 006950 mmol EDTA mL 006950 mmol EDTA mL Amnt Pb Amnt Cd 2007... View full answer
Get step-by-step solutions from verified subject matter experts
Document Format (1 attachment)
927-E-C-E-C-P (834).docx
120 KBs Word File
