(a) Draw the reaction of methyl -D-fructofuranoside with periodic acid, and predict the products. (b) Draw the...
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(b) Draw the structure of a hypothetical methyl -D-fructopyranoside, and predict the products from periodic acid oxidation.
(c) The reaction of methyl -D-glucopyranoside with periodic acid (shown above) gives only the D-(+) enantiomer of glyceraldehyde (among other products). If you oxidized an aldohexose glycoside with periodic acid and one of the products was the L-(-) enantiomer of glyceraldehyde, what would that tell you about the sugar?
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a b Production of one equivalent of formic acid and two fragments c...View the full answer
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