For each NMR spectrum, propose a structure consistent with the spectrum and the additional information provided.
(a) Elemental analysis shows the molecular formula to be C8H7OCl. The IR spectrum shows a moderate absorption at 1602 cm-1 and a strong absorption at 1690 cm-1.

(b) The mass spectrum shows a double molecular ion of ratio 1:1 at m/z 184 and 186.

Transcribed Image Text:

200 180 160 140 100 80 60 40 20 0 CDCl (a) CsH-OCi 10 0 δ (ppm) 200 180 160 140 100 80 60 40 20 0 CDCI3 10 6 4 0 80 ppm)