Show that bimolecular reactions between nonlinear molecules are much slower than between atoms even when the activation
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Show that bimolecular reactions between nonlinear molecules are much slower than between atoms even when the activation energies of both reactions are equal. Use transition state theory and make the following assumptions. (1) All vibrational partition functions are close to unity; (2) all rotational partition functions are approximately 1 X 101.S, which is a reasonable order of magnitude number; (3) the translational partition function for each species is 1 x 1026.
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AB C P kT k2 x4T NART de e ERT 2452 K 9A9B We assume that the only factor that changes between the ...View the full answer
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