a. Derive the two-constant Margules equations for the activity coefficients of a binary mixture (Eqs. 9.5-7). b.

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a. Derive the two-constant Margules equations for the activity coefficients of a binary mixture (Eqs. 9.5-7).

RT In  = ax + x RT In 2 = 0x + 3x (9.5-7)

b. Derive Eqs. 9.5-9. 

In Yi =  1+   . 2. 2 and ln 72 = = 1+    2 (9.5-9)

c. Use the results of part (b) to derive van Laar expressions for the activity coefficients of a ternary mixture (Eq. A9.2-2).

- ( Vi = OG  T,Nj (9.2-2)

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