The reactions of ozone were studied in the presence of alkenes (from R. Atkinson et al., Int. J. Chem. Kinet., 15(8), 721). The data in Table P7-10C are for one of the alkenes studied, cis-2-butene. The reaction was carried out isothermally at 297 K. Determine the rate law and the values of the rate-law parameters.

TABLE P7-10C RATE AS A FUNCTION OF OZONE AND BUTENE CONCENTRATIONS

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Run 1 1.5 Ozone Rate (molls dmx107) (mol/dm) 2 3.2 3 3.5 4 5.0 5 8.8 Ozone Concentration 6 4.7- 0.01 0.02 0.015 0.005 0.001 0.018 Butene Concentration (mol/dm) 10-12 10-11 10-10 10-9 10-8 10-9