What if you were asked to sketch or explain the difference in the temperaturetime trajectories and to
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What if you were asked to sketch or explain the difference in the temperature–time trajectories and to find the catalyst lifetimes (say a = 0.1) for first- and for second-order decay when EA = 35 kcal/mol, Ed = 10 kcal/mol, kd0 = 0.01 day–1, and T0 = 400 K? What would you say? Describe how the trajectory of the catalyst lifetime would change if EA = 10 kcal/mol and Ed = 35 kcal/mol? At what values of kd0 and ratios of Ed to EA would temperature–time trajectories not be effective? Describe what your temperature–time trajectory would look like if n = 1 + Ed/EA?
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