For the purpose of analyzing the effects of recycle on process economics, consider a variation from the

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For the purpose of analyzing the effects of recycle on process economics, consider a variation from the process flowchart that takes the synthesis gas leaving the MUG compressor directly to the MSR.

Suppose that the synthesis gas fed to the MSR is 5 mole% methane, 25% CO, 5% CO2, and the remainder hydrogen, and that the product stream leaving the MSR is at 250°C and 7.5 MPa. Also, for the time being, ignore all reactions in the MSR except for that given by Equation 13.3, which is governed by the equilibrium relationship:

YCH;OH Kø133 %3D 13.3 YcoV, P2 Усо Ун


Where


T is temperature in K, P is pressure in atm, and Kϕ13.3 is a term that accounts for deviations from ideal gas behavior. Assume Kϕ13.3 = 1.0 and determine the composition of the product stream from the MSR and the conversions (%) of CO and H2. Based on these results, comment on the rationale for the recycle loop discussed in the process description.

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Elementary Principles of Chemical Processes

ISBN: 978-0471720638

3rd Edition

Authors: Richard M. Felder, Ronald W. Rousseau

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