One step of the manufacturing of silicon solar cells is the molecular diffusion (doping) of elemental phosphorous

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One step of the manufacturing of silicon solar cells is the molecular diffusion (doping) of elemental phosphorous (P) into crystalline silicon to make an n-type semiconductor. This Pdoped layer needs to be at least 0.467 μm into the 200-μm thick wafer. The present diffusion process is carried out at 1000oC. Data for the total amount of phosphorous atoms loaded into the silicon wafer vs. time at 1000oC are presented in the figure below. The maximum solubility of phosphorous within crystalline silicon is 1.0 × 1021P atoms/cm3at 1000oC. The square silicon wafer has a surface area of 100 cm2(10 cm/side). Initially, there is no phosphorous impurity in the crystalline silicon. What is the concentration of P atoms (atoms P/cm3) doped into the silicon at a depth of 0.467 μm after 40 min, based on the data provided?

6.0E+18 5.0E+18 4.0E+18 3.0E+18 2.0E+18 1.0E+18 0.0E+00 100 20 40 60 80 t1/2 (sec)2 ma(t) (total atoms P in silicon)

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Fundamentals Of Momentum Heat And Mass Transfer

ISBN: 9781118947463

6th Edition

Authors: James Welty, Gregory L. Rorrer, David G. Foster

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