This problem re-examines the dirigible in Example 2-4. The balloon contains 5000 moles of helium, which can

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This problem re-examines the dirigible in Example 2-4. The balloon contains 5000 moles of helium, which can be modeled as an ideal gas with CP* = (5/2)R at the conditions in this problem. The dirigible is initially at T = 25°C and P = 1 atm. The dirigible flies slowly enough that all changes to the helium are reversible. Find Q, W, ΔU,ΔH, and ΔS for the helium if its final state is:

A. T = 15°C and P = 1 atm. Pressure is uniform throughout the process.

B. T = 25°C and P = 0.9 atm. Temperature is uniform throughout the process.

Example 2-4

The balloon portion of a dirigible is filled with 5000 moles of helium (Figure 2-13). Ini tially, the helium is at P = 1 atm and T = 25°C. As the dirigible gains altitude, the pres sure drops to P = 0.95 atm, and the temperature drops to T = 15°C. Find the changes in volume, internal energy, and enthalpy for the helium in this process, assuming helium has a constant ideal gas heat capacity of C*V = (1.5)R. N = 5000 moles of He; P = 0.95 atm; T = 15C a N = 5000 moles of He; P = 1 atm; T = 25C FIGURE 2-13 Schematic

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