A classic experiment in equilibrium studies dating from 1862 involved the reaction in solution of ethanol (C

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A classic experiment in equilibrium studies dating from 1862 involved the reaction in solution of ethanol (C2H5OH) and acetic acid (CH3COOH) to produce ethyl acetate and water.

CH5OH + CH3COOH CH3COOCH5 + HO

The reaction can be followed by analyzing the equilibrium mixture for its acetic acid content.

2 CH3COOH(aq) + Ba(OH)2(aq)  Ba(CH3COO)2(aq) + 2 HO(1)

In one experiment, a mixture of 1.000 mol acetic acid and 0.5000 mol ethanol is brought to equilibrium. A sample containing exactly one-hundredth of the equilibrium mixture requires 28.85 mL 0.1000 M Ba(OH)2 for its titration. Calculate the equilibrium constant, Kc, for the ethanol-acetic acid reaction based on this experiment.

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General Chemistry Principles And Modern Applications

ISBN: 9780132931281

11th Edition

Authors: Ralph Petrucci, Jeffry Madura, F. Herring, Carey Bissonnette

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