(A) Use information from Figure 22-17 to decide whether the nitrite anion, NO 2 , disproportionates...
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(A) Use information from Figure 22-17 to decide whether the nitrite anion, NO2–, disproportionates spontaneously in basic solution to NO3– and NO. Assume standard-state conditions.
(B) Does HNO2 spontaneously disproportionate to NO3– and NO in acidic solution? Assume standard-state conditions. Use data from Figure 22-17.
Figure 22-17
Transcribed Image Text:
Acidic solution ([H+] = 1 M): +5 +3 -2 +4 +2 +1 0 - 1 1.275 V 0.803 V 1.065 V 0.996 V 1.591 V 1.766 V-1.87 V NO3-N₂O4 HNO₂NON₂ON₂NH3OHN2H5†————— NH4+ 1.42 V -3 Basic solution ([OH-] = 1 M): +5 +4 +3 +2 +1 0 - 1 -0.86 V 0.867 V -0.46 V 0.76 V 0.94 V-3.04 V NO3-N₂04NO₂ -NON₂0N₂NH₂OHN₂H4NH3 -2 0.73 V -3 0.10 V
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Based on Figure 2217 the reduction potential of NO3 to NO i...View the full answer
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Related Book For
General Chemistry Principles And Modern Applications
ISBN: 9780132931281
11th Edition
Authors: Ralph Petrucci, Jeffry Madura, F. Herring, Carey Bissonnette
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