Methyl nitrate, CH 3 NO 3 , is used as a rocket propellant. The skeletal structure of

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Methyl nitrate, CH3NO3, is used as a rocket propellant. The skeletal structure of the molecule is CH3ONO2. The N and three O atoms all lie in the same plane, but the CH3 group is not in the same plane as the NO3 group. The bond angle C—O—N is 105°, and the bond angle O—N—O is 125°. One nitrogen-to-oxygen bond length is 136 pm, and the other two are 126 pm.

(a) Draw a sketch of the molecule showing its geometric shape.

(b) Label all the bonds in the molecule as σ or π and indicate the probable orbital overlaps involved.

(c) Explain why all three nitrogen-to-oxygen bond lengths are not the same.

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General Chemistry Principles And Modern Applications

ISBN: 9780132931281

11th Edition

Authors: Ralph Petrucci, Jeffry Madura, F. Herring, Carey Bissonnette

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