Radioactive decay and mass spectrometry are often used to date rocks after they have cooled from a

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Radioactive decay and mass spectrometry are often used to date rocks after they have cooled from a magma. 87Rb has a half-life of 4.88 x 1010 years and follows the radioactive decay

87Rb 87 Sr+ B

A rock was dated by assaying the product of this decay. The mass spectrum of a homogenized sample of rock showed the 87Sr/86Sr ratio to be 2.25. Assume that the original 87Sr/86Sr ratio was 0.700 when the rock cooled. Chemical analysis of the rock gave 15.5 ppm Sr and 265.4 ppm Rb, using the average atomic masses from a periodic table. The other isotope ratios were 86Sr/88Sr = 0.119 and 84Sr/88Sr = 0.007. The isotopic ratio for 87Rb/85Rb is 0.330. The isotopic masses are as follows:

Isotope 87 Rb 85 Rb 885r 865r 845r 875r Sr Atomic Mass, u 86.909 84.912 87.906 85.909 83.913 86.909

Calculate the following:

(a) The average atomic mass of Sr in the rock 

(b) The original concentration of Rb in the rock in ppm 

(c) The percentage of rubidium-87 decayed in the rock 

(d) The time since the rock cooled.

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General Chemistry Principles And Modern Applications

ISBN: 9780132931281

11th Edition

Authors: Ralph Petrucci, Jeffry Madura, F. Herring, Carey Bissonnette

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