Some electrochemical cells employ large biological molecules known as enzymes. An enzyme increases the rate of a

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Some electrochemical cells employ large biological molecules known as enzymes. An enzyme increases the rate of a biochemical reaction. Some enzymes perform oxidation reactions, and some others perform reduction reactions. An electrochemical cell based on the use of enzymes is given in the following illustration.

Glucose oxidase H 2e- Glucose Gluconolactone 4 Glucose oxidase-coated anode (carbon nanotube) ?V f PEM O +

The half-cell reactions for electrochemical cell and the corresponding reduction potentials are given below. The symbol E°’ is used here because these values refer to the biological standard state: 37 °C, aH+ = 10-7, all other activities equal to 1.

Anode: C6H1006(aq) Cathode: + 2H+ (aq) + 2 e O(g) + 4H+ (aq) + 4 e C6H206(aq) E* 2 HO(1) = -0.3583 V E = 0.82

(a) Write an equation for the overall reaction occurring in this electrochemical cell.

(b) Write a cell diagram for this battery.

(c) Calculate the standard cell potential for the electrochemical reaction.

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General Chemistry Principles And Modern Applications

ISBN: 9780132931281

11th Edition

Authors: Ralph Petrucci, Jeffry Madura, F. Herring, Carey Bissonnette

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