We have seen that complex formation can stabilize oxidation states. An important illustration of this fact is

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We have seen that complex formation can stabilize oxidation states. An important illustration of this fact is the oxidation of water in acidic solutions by Co3+(aq) but not by [Co(en)3]3+. Use the following data.

[Co(HO)6]+ + e [Co(HO)6]2+ + 3 en [Co(HO)6]3+ + 3 en [Co(H,O)%]2+ Calculate E for the reaction [Co(en)3]+ + e

Show that [Co(en)3]3+ is stable in water but Co3+(aq) is not.

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General Chemistry Principles And Modern Applications

ISBN: 9780132931281

11th Edition

Authors: Ralph Petrucci, Jeffry Madura, F. Herring, Carey Bissonnette

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