(a) Os 5 (CO) 18 has a metal framework consisting of three edge-sharing triangles (a raft structure)....
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(a) Os5(CO)18 has a metal framework consisting of three edge-sharing triangles (a raft structure). Show that the valence electron count for this raft is consistent with the number available.
(b) Figure 24.33 shows the metal core of [Ir8(CO)22]2−. What would be an appropriate electron-counting scheme for this cluster?
Figure 24.43.
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