(a) Os 5 (CO) 18 has a metal framework consisting of three edge-sharing triangles (a raft structure)....

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(a) Os5(CO)18 has a metal framework consisting of three edge-sharing triangles (a raft structure). Show that the valence electron count for this raft is consistent with the number available.

(b) Figure 24.33 shows the metal core of [Ir8(CO)22]2−. What would be an appropriate electron-counting scheme for this cluster?


Figure 24.43.

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Inorganic Chemistry

ISBN: 9781292134147

5th Edition

Authors: Catherine Housecroft

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