Calculate the rate constants for outer sphere reactions from the following data Compare your results to the measured values in the last column Reaction Cr Fe W(CN), Ce(IV) Fe(CN), MnO Fe(phen), Ce(IV) k ,, dm mol s 2x 10 4 x 10 7 410 3 x 10 k dm E V mol s 4 0 4 4 3 10 4 4 1 18 0 54 1 30 0 66 kobs d...

To calculate the rate constants for outersphere reactions we can use the Marcus crossrelation equati ...

Calculate the rate constants for outer-sphere reactions from the following data. Compare your results to the measured

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Calculate the rate constants for outer-sphere reactions from the following data. Compare your results to the measured values in the last column.

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Inorganic Chemistry

ISBN: 9780198768128

7th Edition

Authors: Mark Weller, Tina Overton, Jonathan Rourke

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Question Posted: Aug 03, 2023 06:49 AM

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Calculate the rate constants for outer-sphere reactions from the following data. Compare your results to the measured

Question:

Reaction Cr²+ + Fe³+ [W(CN),]++ Ce(IV) [Fe(CN),]+ +[MnO₂] [Fe(phen), ]²+ + Ce(IV) k.,,/dm³ mol ¹s¹ 2x 10-⁹ >4 x 10¹ 7.4×10² >3 x 10² k₂/dm³ E/V mol ¹s¹ 4.0 4.4 3× 10³ 4.4 +1.18 +0.54 +1.30 +0.66 kobs/dm³ mol ¹s¹ 2.3 × 10³ >10⁰ 1.7 x 105 1.4 x 105

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Inorganic Chemistry

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