Determine the configuration (in the form t 2g x e g y or e x t 2
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Determine the configuration (in the form t2gx egy or ext2y , as appropriate), the number of unpaired electrons, and the ligandfield stabilization energy in terms of ΔO or ΔT and P for each of the following complexes. Use the spectrochemical series to decide, where relevant, which are likely to be high-spin and which low-spin.
(a) [Co(NH3)6]3+,
(b) [Fe(OH2)6]2+,
(c) [Fe(CN)6]3−,
(d) [Cr(NH3)6]3+,
(e) [W(CO)6],
(f) Tetrahedral [FeCl4]2−,
(g) Tetrahedral [NiCl4]2−.
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Related Book For
Inorganic Chemistry
ISBN: 9780198768128
7th Edition
Authors: Mark Weller, Tina Overton, Jonathan Rourke
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