Determine the configuration (in the form t 2g x e g y or e x t 2

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Determine the configuration (in the form t2gx egy or ext2y , as appropriate), the number of unpaired electrons, and the ligandfield stabilization energy in terms of ΔO or ΔT and P for each of the following complexes. Use the spectrochemical series to decide, where relevant, which are likely to be high-spin and which low-spin.

(a) [Co(NH3)6]3+

(b) [Fe(OH2)6]2+

(c) [Fe(CN)6]3−

(d) [Cr(NH3)6]3+,

(e) [W(CO)6], 

(f) Tetrahedral [FeCl4]2−

(g) Tetrahedral [NiCl4]2−.

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Inorganic Chemistry

ISBN: 9780198768128

7th Edition

Authors: Mark Weller, Tina Overton, Jonathan Rourke

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