Discuss each of the following observations: (a) Although Co 2+ (aq) forms the tetrahedral complex [CoCl 4

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Discuss each of the following observations:

(a) Although Co2+ (aq) forms the tetrahedral complex [CoCl4]2− on treatment with concentrated HCl, Ni2+ (aq) does not form a similar complex.

(b) E° for the half-reaction:

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depends on the pH of the solution, being most positive in strongly acidic medium.

(c) E° for the Mn3+/Mn2+ couple is much more positive than that for Cr3+/Cr2+ or Fe3+/Fe2+.

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Inorganic Chemistry

ISBN: 9781292134147

5th Edition

Authors: Catherine Housecroft

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