Estimate the spin-only contribution to the magnetic moment for each complex in Exercise 20.1. Data from Exercises
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Estimate the spin-only contribution to the magnetic moment for each complex in Exercise 20.1.
Data from Exercises 20.1
Determine the configuration (in the form t2gx egy or ext2y , as appropriate), the number of unpaired electrons, and the ligandfield stabilization energy in terms of ΔO or ΔT and P for each of the following complexes. Use the spectrochemical series to decide, where relevant, which are likely to be high-spin and which low-spin.
[Co(NH3)6]3+,
[Fe(OH2)6]2+,
[Fe(CN)6]3−,
[Cr(NH3)6]3+,
[W(CO)6],
Tetrahedral [FeCl4]2−,
Tetrahedral [NiCl4]2−.
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Inorganic Chemistry
ISBN: 9780198768128
7th Edition
Authors: Mark Weller, Tina Overton, Jonathan Rourke
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