For solid Ba[CSe 3 ], the vibrational wavenumbers and assignments for the [CSe 3 ] 2 ion
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For solid Ba[CSe3], the vibrational wavenumbers and assignments for the [CSe3]2− ion are 802 (E', stretch), 420 (A2''), 290 (A1') and 185 (E', deformation) cm−1.
(a) Based on these assignments, deduce the shape of the [CSe3]2− ion.
(b) Draw diagrams to illustrate the modes of vibration of [CSe3]2−.
(c) Which modes of vibration are IR active?
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a Based on the vibrational wavenumbers and assignments provided we can deduce the shape of the CSe32 ion The wavenumbers and their corresponding assig...View the full answer
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