Second order rate constants, k 2 , for the reaction of trans-[Pt(PEt 3 ) 2 Ph(MeOH)] +

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Second order rate constants, k2, for the reaction of trans-[Pt(PEt3)2Ph(MeOH)]+ with pyridine (py) in MeOH to give trans-[Pt(PEt3)2Ph(py)]+ vary with temperature as shown below. Use the data to determine the activation enthalpy and activation entropy for the reaction.

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Inorganic Chemistry

ISBN: 9781292134147

5th Edition

Authors: Catherine Housecroft

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