The pressure dependence of the replacement of chlorobenzene (PhCl) by piperidine in the complex [W(CO) 4 (PPh
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The pressure dependence of the replacement of chlorobenzene (PhCl) by piperidine in the complex [W(CO)4(PPh3)(PhCl)] has been studied. The volume of activation is found to be +11.3 cm3 mol−1. What does this value suggest about the mechanism?
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The volume of activation 113 cm3 mol1 provides important information about the mechanism of the reac...View the full answer
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Related Book For 
Inorganic Chemistry
ISBN: 9780198768128
7th Edition
Authors: Mark Weller, Tina Overton, Jonathan Rourke
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