TheESImass spectrum(positivemode) of the compound shown below exhibits two peaks at m/z 299.2 (base peak) and 321.1.

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TheESImass spectrum(positivemode) of the compound shown below exhibits two peaks at m/z 299.2 (base peak) and 321.1. 

(a) What is a ‘base peak’? 

(b) Suggest how the observed peaks arise. [Data: C.J. Sumby et al. (2009) Tetrahedron, vol. 65, p. 4681.]

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Data from Appendix 5

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Inorganic Chemistry

ISBN: 9781292134147

5th Edition

Authors: Catherine Housecroft

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