Treatment of TiCl 4 at low temperature with EtMgBr gives an organometallic compound that is unstable above
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Treatment of TiCl4 at low temperature with EtMgBr gives an organometallic compound that is unstable above −70°C. However, treatment of TiCl4 at low temperature with MeLi or LiCH2SiMe3 gives organometallic compounds that are stable at room temperature. Rationalize these observations.
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ANSWER The observations described can be rationalized based on the nature of the organometallic compounds formed and the steric and electronic factors ...View the full answer
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Related Book For 
Inorganic Chemistry
ISBN: 9780198768128
7th Edition
Authors: Mark Weller, Tina Overton, Jonathan Rourke
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