The (1) + (2) system forms an azeotrope at x 1 = 0.75 and 80C. At 80C,

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The (1) + (2) system forms an azeotrope at x1 = 0.75 and 80°C. At 80°C, P1sat = 600 mmHg, P2sat = 900 mmHg. The liquid phase can be modeled by the one-parameter Margules equation.

(a) Estimate the activity coefficient of component 1 at x1 = 0.75 and 80 °C.

(b) Qualitatively sketch the P-x-y and T-x-y diagrams that you expect.

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