The excess Gibbs energy for binary systems consisting of liquids not too dissimilar in chemical nature is represented to a reasonable approximation by the equation:

where A is a function of temperature only. For such systems, it is often observed that the ratio of the vapor pressures of the pure species is nearly constant over a considerable temperature range. Let this ratio be r, and determine the range of values of A, expressed as a function of r, for which no azeotrope can exist. Assume the vapor phase to be an ideal gas.

Transcribed Image Text:

GE /RT=Ax1x2