The following is a set of data for the following reaction at 25 C. (CH 3

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The following is a set of data for the following reaction at 25 C.

(CH3)3CBr + H2O → (CH3)3COH + HBr.

Using linear least squares, determine whether the reaction obeys first-order, second-order, or third-order kinetics and find the value of the rate constant.

Time/h              [(CH3)3CBr]/mol l−1
0.............................................0.1051
5.............................................0.0803
10...........................................0.0614
15...........................................0.0470
20...........................................0.0359
25...........................................0.0274
30...........................................0.0210
35...........................................0.0160
40...........................................0.0123

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