The , to , interconversion of unsaturated ketones is catalyzed by base as well as

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The α, β  to β, γ interconversion of unsaturated ketones is catalyzed by base as well as by acid. Propose a mechanism.


Problem 11.29

Nonconjugated β, γ-unsaturated ketones such as cyclohex-3-enone are in an acid-catalyzed equilibrium with their conjugated α, β-unsaturated isomers. Propose a mechanism for the acid-catalyzed interconversion.image

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