When benzyl alcohol ( max = 258 nm, = 520) is dissolved in H 2 SO

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When benzyl alcohol (λmax = 258 nm, ϵ = 520) is dissolved in H2SO4, a colored solution is obtained that has a different UV spectrum: λmax = 442 nm, ϵ = 53,000. When this solution is added to cold NaOH, the original spectrum of benzyl alcohol is restored. Suggest a structural basis for these observations.

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Organic Chemistry

ISBN: 9781936221349

6th Edition

Authors: Marc Loudon, Jim Parise

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