The density of states (DOS) of pyrite, crystalline FeS 2 (as calculated by Eyert et al, Physical

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The density of states (DOS) of pyrite, crystalline FeS2(as calculated by Eyert et al, Physical Review B 55 (1998): 6350, is shown next. The highest occupied energy level corresponds to zero energy. Based on the DOS, is pyrite an insulator, a conductor, or a semiconductor? Also, how does the DOS support the localized-bonding view that some iron valence orbitals are nonbonding?

Fe 3d 30 pyrite, FeS2 Fe 3d and S 3p Fe 3d and S 3p 10-S 3s -15 -10 -5 Energy (eV) Density of states (number/eV)

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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