Use the GibbsDuhem equation to derive the GibbsDuhemMargules equation where f is the fugacity. Use the relation

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Use the Gibbs–Duhem equation to derive the Gibbs–Duhem–Margules equation

where f is the fugacity. Use the relation to show that, when the fugacities are replaced by pressures, if Raoult’s law applies to one component in a mixture it must also apply to the other.

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Physical Chemistry

ISBN: 9780716787594

8th Edition

Authors: Peter Atkins, Julio De Paula

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Question Posted: Sep 13, 2022 01:50 AM

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Use the GibbsDuhem equation to derive the GibbsDuhemMargules equation where f is the fugacity. Use the relation

Question:

a Infa Ə In xA P,T a lnfB a ln XB P,T

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Physical Chemistry

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