Use the GibbsHelmholtz equation to find an expression for d ln x A in terms of dT.

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Use the Gibbs–Helmholtz equation to find an expression for d ln xA in terms of dT. Integrate d ln xA from xA = 0 to the value of interest, and integrate the right–hand side from the transition temperature for the pure liquid A to the value in the solution. Show that, if the enthalpy of transition is constant, then eqns 5.33 and 5.36 are obtained.

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Physical Chemistry

ISBN: 9780716787594

8th Edition

Authors: Peter Atkins, Julio De Paula

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