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A 5.00 mL sample of brandy was diluted to 1.000 L in a volumetric flask. The ethanol, C 2 H 5 OH, in a 25.00

A 5.00 mL sample of brandy was diluted to 1.000 L in a volumetric flask. The ethanol, C 2 H 5 OH, in a 25.00 mL aliquot of the diluted solution was distilled into 50.00 mL of 0.02 M K 2 Cr 2 O 7 and oxidized to acetic acid with heating, the reaction is: 3C 2 H 5 OH+2Cr 2 O 7 2- +16H + -->4Cr 3+ +3CH 3 COOH+11H 2 O After cooling, 20.00 mL of 0.1253 M Fe 2+ was pipetted into the flask. The excess Fe 2+ was then titrated with 7.46 mL of the K 2 Cr 2 O 7 solution to a diphenylamine sulfonic acid end point. Calculate the percent weight/volume of C 2 H 5 OH in the brandy.

C 2 H 5 OH: FM=46.07 g/mol

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