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You added 0.05ml of 0.10 M AgNO 3 to 4.0ml of 2.0 M NaCland formed a saturated solution of AgCl (s): AgCl (s) Ag +

You added 0.05ml of 0.10 M AgNO 3 to 4.0ml of 2.0 M NaCland formed a saturated solution of AgCl (s):

AgCl (s) <------> Ag + (aq) +Cl - (aq) K= Ksp

Using this saturated solution as the test solution ou set up thefollowing cell

Ag|Ag + (test solution afterreaction)||Ag + (1.0M)|Ag

and measured Ecell = 0.61 V.

a) Using the measured value of Ecell, calculate the equilibrium[Ag+] (ie. of the test solution after mixing)

b) Calculate the equilibrium concentration of Cl-.

c) Calculate the Ksp.

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a Use the formula E E 00592VnlogAg dil Ag conc 061V 0 00592V1 logAg ... blur-text-image

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