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Problem Desulfurization unit of a reforming process mole balance, extent of the reaction at equilibrium and equilibrium conversion calculation
Consider the following gasphase reaction between methyl mercaptan and hydrogen in a desulfurization unit of a reforming process to form methane and hydrogen sulfide takes place in a fixed bed reactor.
desulfurization reaction
A
BC
At equilibrium, the mole fractions of the four reactive species are related by the reaction equilibrium constant assumed value
i Draw and label a flow diagram of the desulfurization unit only
ii Suppose the feed to the reactor consists of ;; and moles of and respectively. Write expressions for the moles of each species in the final product, and in terms of incoming moles and the extent be of the reaction.
iii Then use these expressions and the given equilibrium constant to derive an equation for the equilibrium extent of reaction, in terms of ;; and
iv If the feed to the reactor contains equimolar quantities of mercaptan and hydrogen, calculate the equilibrium fractional conversion.
viv It is desired to produce mol of methane starting with mol of mercaptan If the reaction proceeds to equilibrium, how much hydrogen must be fed? What is the composition of the final product?
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