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1 2 . 2 1 Consider a closed vessel initially containing 1 mol of tetrahydrofuran at 5 0 oC and 5 2 kPa. Imagine that

12.21 Consider a closed vessel initially containing 1 mol of tetrahydrofuran at 50oC and 52 kPa. Imagine that pure chloroform is slowly added at constant temperature and pressure until the vessel contains 1 mol tetrahydofuran and 9 mol chloroform. Describe the evolution of phases and phase compositions during this process. Comment on the practical feasibility of carrying out such a process. What sort of device would be required ? How would the total system volume change during this process ? At what composition would the system volume reach its maximum value?

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