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1 5 . 1 3 . The International Critical Tables, Vol. III, p . 3 1 3 , lists the boiling points for mixtures of

15.13. The International Critical Tables, Vol. III, p.313, lists the boiling points for mixtures of
acetaldehyde and ethyl alcohol at various pressures. The data are summarized below for
mixtures containing 80 mole% ethyl alcohol in the liquid.
From these data determine the molar enthalpy of vaporization of ethyl alcohol at 320.7
K, from a liquid mixture containing 80% ethyl alcohol. [That is, what is (?bar(H)V-bar(H)2)
alcohol?]
Note: The vapor phase may be considered to be an ideal-gas mixture, but the liquid phase
is a non-ideal solution. The correct answer is approximately roughly 4*10^4 J/mol.
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