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1 8 - 2 The hydrolysis of methyl acetate ( A ) in dilute aqueous solution to form methanol ( B ) and acetic acid

18-2 The hydrolysis of methyl acetate (A) in dilute aqueous solution to form methanol (B) and acetic acid (C) is to take place in a batch reactor operating isothermally. The reaction is reversible, pseudo-first-order with respect to acetate in the forward direction (:1.8210-4s-1}, and first-order with respect to each product species in the reverse direction )=(4.4910-4(L)mol-1s-1. The feed contains only A in water, at a concentration of 0.050molL-1. Determine the size of the reactor required, if the rate of product formation is to be 100molh-1 on a continuing basis, the down-time per batch is 30min, and the optimal fractional conversion (i.e., that which maximizes production) is obtained in each cycle.
18-3 The reaction in problem 18-2 is to be conducted in an isothermal 60-L PFR, with a feed rate (FAo) of 0.75molmin-1. All other data (cAo,kr,kf) remain the same.
(a) Calculate the fractional conversion fA at the outlet of the reactor.
(b) What is the maximum possible value of fA, regardless of reactor type or size?
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