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1. Acid rain refers to precipitation events in which the rainwater has a relatively low pH. The acidic environment inside a rain droplet is produced
1. Acid rain refers to precipitation events in which the rainwater has a relatively low pH. The acidic environment inside a rain droplet is produced when acid precursors present in the air (such as SO2 ) are absorbed into the droplet. In this problem, we will consider the absorption of SO2 into a spherical water droplet exposed to air with SO2. A 2 mm-radius water droplet initially containing no SO2 is in a cloud that is suddenly exposed to air with an SO2 mole fraction of 0.01 at 15C and 1 atm. At 15C, the diffusivity of SO2 in liquid water is 2.3105cm2/s. Equilibrium between air and water is represented by Henry's law: PA=50xA, where PA is the partial pressure of SO2 in the air (atm), and xA is its mole fraction in the liquid. The molar density of liquid water is 0.0556 mol/cm3 (a) Determine the time required for the center of the droplet to reach 95% of the steady-state concentration of SO2 (b) Calculate the total number of moles of SO2 in the water droplet at that time. You may assume that external convection produced by the relative motion between the air and the droplet is very fast, and that the SO2 will not undergo chemical reactions during its absorption
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