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1. CH 4 (g) + 2O 2 (g) CO 2 (g) + 2H 2 O(l) Determine the temperature ( in K) such that the reaction

1. CH4(g) + 2O2(g) CO2(g) + 2H2O(l) Determine the temperature ( in K) such that the reaction is in equilibrium in its standard states

Compound Hf (kJ mol-1) S (J mol-1 K-1)
CH4 (g) -74.87 188.66
O2 (g) 0.00 205.70
CO2 (g) -393.51 213.74
H2O (l) -285.83 69.91

2.Consider the chemical reaction and thermochemical information and initial partial pressures of the reaction components given below: Cl2O(g) + O2(g) Cl2(g) + O3(g)

Hf (kJ/mol) S (J mol-1 K-1) P (atm)
Cl2O 87.86 267.89 0.235
O2 0.00 205.70 0.859
Cl2 0.00 223.08 4.95
O3 142.67 238.92 7.48

Determine G (in kJ) for this reaction at 505.29 K. Assume Hf and S do not vary as a function of temperature. Report your answer to two decimal places

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