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1. Construct a titration curve for 50.0 mL of 0.015 M Fe2+ with 0.030 M EDTA in a solution buffered at pH 7.0. The KFey
1. Construct a titration curve for 50.0 mL of 0.015 M Fe2+ with 0.030 M EDTA in a solution buffered at pH 7.0. The KFey for Fey2- is 1.2 x 1012 at 25C. A. Preliminary information needed: (a) What is the reaction for this titration? (b) (Fe) initially = (c) (nedta)added to reach eq.pt. (d) (VEDTA)eq.pt . = (e) K'Fey= pH Ay4- pH ayu- pH 9y4- pH ay4- -4 1.0 -18 1.4 x 10 4.0 -9 3.0 x 10 7.0 3.8 x 10 10.0 0.30 -14 2.0 2.6 x 10 5.0 -7 2.9 x 10 8.0 4.2 x 10 11.0 0.81 -11 3.0 2.1 x 10 6.0 -5 1.8 x 10 9.0 0.041 12.0 0.98 B. Calculate the pFe after addition of the following volumes of the EDTA solution. (a) (VEDTA)added = 0.00 mL pFe = (b) (VEDTA)added = 20.00 mL pFe = (c) (VEDTA)added = 25.00 mL pFe = (d) (Vedta)added = 30.00 mL pFe =
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