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1. Hydrogen peroxide reacts with thiosulfate ion in slightlyacidic solution as follows: H 2 O 2 + 2S 2 O 3 2? + 2 H

1. Hydrogen peroxide reacts with thiosulfate ion in slightlyacidic solution as follows:

H2O2 + 2S2O32?+ 2 H+? 2H2O + S4O62?

The reaction rate is independent of the hydrogen ionconcentration in the pH range 4 to 6. The following data wereacquired at 25 ?C and pH 5.0. Initial concentrations:[H2O2] = 0.036 mol/L,[S2O32-] = 0.0204 mol/L

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(a) What is the overall order of the reaction?

(b) What is the rate constant?

No information was given for [H2O2] for the course ofthe reaction

2. For the reaction, where M is an inert gas atom (such as He orAr),

O + NO + M ? NO2 + M

The rate constant exhibits the following temperaturebehavior:

at 300 K, k = 6 ? 109L2mol?2s?1; at 1000 K, k = 3 x1010 L2mol?2s?1.

Determine the activation energy and the prexponential factorusing the Arrhenius equation.

Time (min) [SO3-] (mol/L) 16 36 43 52 10.30 5.18 4.16 3.13

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