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1. Using the Arrhenius equation rather than the Eyring equation, show that the Curtin-Hammett equation can be expressed in terms of Arrhenius activation energies and
1. Using the Arrhenius equation rather than the Eyring equation, show that the Curtin-Hammett equation can be expressed in terms of Arrhenius activation energies and the equilibrium free energy difference between equilibrating substances A and B.
2. Use the Curtin-Hammett equation to respond to the following. (a) Determine PA/PB if Keq = 1 and kB = 10 kA. (b) Determine Keq when PA/PB = 10 and kB = 10 kA. Show your work, of course.
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