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2 . 1 0 Ammonia is being cracked on a solid catalyst according to the reaction 2 N H 3 N 2 + 3 H

2.10 Ammonia is being cracked on a solid catalyst according to the reaction
2NH3N2+3H2
At one place in the apparatus, where the pressure is 1std atm abs and the temperature 200C, the
analysis of the bulk gas is 33.33%NH3(A),16.67%N2(B), and 50.00%H2(C) by volume. The
circumstances are such that NH3 diffuses from the bulk-gas stream to the catalyst surface, and the
products of the reaction diffuse back, as if by molecular diffusion through a gas film in laminar flow
1mm thick. Estimate the local rate of cracking, kgNH
considered to occur if the reaction is diffusion-controlled (chemical reaction rate very rapid) with the
concentration of NH3 at the catalyst surface equal to zero.
Ans.: 0.0138kgm2*s.
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