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( 2 ) Benzene and toluene form an ideal solution at 2 0 C , but a nonideal solution at 1 2 0 C .

(2) Benzene and toluene form an ideal solution at 20C, but a nonideal solution at 120C. For the latter
solution, we have the following experimental data for the compositions and total vapour pressures:
(a) Knowing that the vapour pressures of pure benzene and toluene are 2.98atm and 1.34atm
at 120C, respectively, estimate the activity coefficients and the activities for the solute and solvent
for a solution with composition xBenzene(liq)=0.40. Discuss carefully the conventions used for the
computation of the activities, and any simplification you had to make.
(b) Estimate the Gmix for preparing the solution with composition xBenzene(liq)=0.40.
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