Question
2. Organic chemists love playing with molecules molecular toys, like TinkerToys, at the molecular scale. e.g. the Nobel prize for chemistry (2016) was won by
2. Organic chemists love playing with molecules molecular toys, like TinkerToys, at the molecular scale. e.g. the Nobel prize for chemistry (2016) was won by Professors Stoddart and Feringa for making, among other toys, rotating motors and self-propelled molecular cars. Among the first molecular toys were compounds resembling B a molecule with a vase structure that can bind to others in a host-guest pairing. B can be prepared from 4-tert-butyl phenol and formaldehyde (CH2=O). (a) Show the synthesis of B starting with phenol. Give specific reagents and the detailed mechanism of the elemental steps that makes each of the four Ar-CH2-Ar bonds (Ar is the substituted benzene in B).
2. Organic chemists love playing with molecules - 'molecular toys', like TinkerToys, at the molecular scale. e.g. the Nobel prize for chemistry (2016) was won by Professors Stoddart and Feringa for making, among other 'toys', rotating motors and self-propelled molecular cars. Among the first molecular toys were compounds resembling B-a molecule with a 'vase structure' that can bind to others in a 'host-guest pairing. B can be prepared from 4-tert-butyl phenol and formaldehyde (CH2=0). (a) Show the synthesis of B starting with phenol. Give specific reagents and the detailed mechanism of the elemental steps that makes each of the four Ar-CH2-Ar bonds (Ar is the substituted benzene in B). 6 pts OH OH OH OH B OH OH HO OHStep by Step Solution
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